Supporting Information For Probing Adsorption Interactions In Metal-Organic Frameworks Using X-ray Spectroscopy
نویسندگان
چکیده
1 Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA 2 Department of Chemical and Biomolecular Engineering, University of California, Berkeley, California 94720-1460, USA 3 Department of Chemistry, University of California, Berkeley, California 94720-1460, USA 4 Laboratoire de Science et Ingénierie des Matériaux et Procédés (SIMaP), UMR CNRS 5266, Grenoble-INP, BP 75, 38402 Saint Martin d'Hères Cedex, France
منابع مشابه
Probing adsorption interactions in metal-organic frameworks using X-ray spectroscopy.
We explore the local electronic signatures of molecular adsorption at coordinatively unsaturated binding sites in the metal-organic framework Mg-MOF-74 using X-ray spectroscopy and first-principles calculations. In situ measurements at the Mg K-edge reveal distinct pre-edge absorption features associated with the unique, open coordination of the Mg sites which are suppressed upon adsorption of ...
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